An evaluation of metallized propellants based on vehicle performance

An analytical study was conducted to determine the improvements in vehicle performance possible by burning metals with conventional liquid bipropellants. These metallized propellants theoretically offer higher specific impulse, increased propellant density and improved vehicle performance compared with conventional liquid bipropellants. Metals considered were beryllium, lithium, aluminum and iron. Liquid bipropellants were H2/O2, N2H4/N2O4, RP-1/O2 and H2/F2. A mission with a delta V = 4267.2 m/sec (14,000 ft/sec) and vehicle with propellant volume fixed at 56.63 cu m (2000 cu ft) and dry mass fixed at 2761.6 kg (6000 lb) was used, roughly representing the transfer of a chemically propelled upper-stage vehicle from a low-Earth orbit to a geosynchronous orbit. The results of thermochemical calculations and mission analysis calculations for bipropellants metallized with beryllium, lithium, aluminum and iron are presented. Technology issues pertinent to metallized propellants are discussed.