Thermal and solutal convection with conduction effects inside a rectangular enclosure

We numerically investigate the effects of various boundary conditions on the flow field characteristics of the physical vapor transport process. We use a prescribed temperature profile as boundary condition on the enclosure walls, and we consider parametric variations applicable to ground-based and space microgravity conditions. For ground-based applications, density gradients in the fluid phase generate buoyancy-driven convection which in turn disrupts the uniformity of the mass flux at the interface depending on the orientation. Heat conduction in the crystal can affect the fluid flow near the interface of the crystal. When considering isothermal source and sink at the interfaces, we observe a diffusive mode and three modes (i.e., thermal, solutal, and thermo-solutal). The convective modes show opposing flow field trends between thermal and solutal convection; theoretically, these trends can be used to achieve a uniform mass flux near the crystal. However, under the physical conditions chosen, the mathematical condition necessary for uniform mass flux cannot be satisfied because of thermodynamic restrictions. When a longitudinal thermal gradient is prescribed on the boundary of the crystal, a non-uniform interface temperature results, which induces a symmetrical fluid flow near the interface for the vertical case. For space microgravity applications, we show that the flow field is dominated by the Stefan wind and a uniform mass flux results at the interface.