Molecular absorption parameters in atmospheric modelling

Molecular spectroscopic parameters are compiled for a number of infrared-active molecules occurring naturally in the terrestrial atmosphere. The following molecules are included in this compilation: water vapor; carbon dioxide; ozone; nitrous oxide; carbon monoxide; methane; and oxygen. The spectral region covered extends from less than 1 micron to the far infrared, and data are presented on more than 100,000 spectral lines. The parameters included in the compilation for each line are: frequency, intensity, half-width, energy of the lower state of the transition, vibrational and rotational identifications of the upper and lower energy states, an isotopic identification, and a molecular identification. Using this data compilation, band model parameters are presented for water vapor, carbon dioxide, and ozone averaged over 20 wavenumber intervals. Using these parameters in a random model formulation, transmittance spectra are provided and compared with both degraded monochromatic calculations and laboratory data.