Kinetics of Open Circuit Processes in Undischarged Li/SOC12 Cells

The kinetics of the heat producing processes in undischarged Li/SOCl2 cells under open circuit conditions were measured by heat-conduction microcalorimetry. The cells studied, Honeywell type G2666 reserve cells, were activated as needed and the rate of open circuit heat output determined as a function of time since activation and temperature. The results at each temperature can be described by an equation of the form q = Bktx where q is the rate of heat output, B is the heat produced per unit of reaction, k and x are empirical constants, and t is the time since activation. Both x and k are found to be functions of temperature; therefore, accelerated testing at elevated temperatures is probably not valid for these cells until the processes involved are better understood.