Strength, Width, and Pressure Shift Measurements of 54 Lines in the Oxygen A-Band

The absorption band of molecular oxygen, centered at 760]en1] nm, is the atmospheric absorber for the Differential Absorption Lidar (DIAL) systems used to measure atmospheric temperature, pressure, and density. To provide accurate line parameters for such systems, a careful spectroscopic study was made of the A-band, with measurements of line strengths, widths, pressure-induced frequency shifts, and collisional narrowing effects. The width and shift parameters were measured over a temperature range of -20 to 100 C so that the temperature dependence of these parameters can also be determined. To analyze the results, a least-squares fiting routine was written to fit standard line profiles to the observed profiles. These measurements, which include the first observations of pressure shifts and collisional narrowing in the band, are an important contribution to lidar system utilizing the A-band.