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Characterization of hot hydrogen-atom reactions by kinetic spectrography.The flash photolysis of hydrogen iodide in the presence of nitrous oxide, carbon dioxide, and water has been investigated by kinetic spectroscopy. Although the fraction of hydrogen iodide dissociated was very large, the only observable intermediate was imidogen. It was demonstrated that the rapid removal of imidogen and the apparent absence of hydroxyl radicals in each case is a result of the following two reactions, respectively: (1) NH + HI yields NH2 + I; and (2) OH + HI yields H2O + I.
Document ID
19720027448
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Tomalesky, R. E.
Sturm, J. E.
(Lehigh University Bethlehem, Pa., United States)
Date Acquired
August 6, 2013
Publication Date
November 1, 1971
Publication Information
Publication: Journal of Chemical Physics
Volume: 55
Subject Category
Chemistry
Accession Number
72A11114
Funding Number(s)
CONTRACT_GRANT: AT(30-1)-2772
Distribution Limits
Public
Copyright
Other

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