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Mechanism of rotational relaxation.A model is presented which describes the characteristic pattern of relaxation of a nonthermal rotational distribution of hydrogen halide, peaked initially at high rotational quantum number J, to a thermal distribution without generating a peak at intermediate J. A method for correcting infrared chemiluminiscence data for modest rotational relaxation is also suggested.
Document ID
19720036007
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Polanyi, J. C.
Woodall, K. B.
(Toronto, University Toronto, Canada)
Date Acquired
August 6, 2013
Publication Date
February 15, 1972
Publication Information
Publication: Journal of Chemical Physics
Volume: 56
Subject Category
Chemistry
Accession Number
72A19673
Funding Number(s)
CONTRACT_GRANT: DRB-9530-104
CONTRACT_GRANT: NGR-52-026-028
Distribution Limits
Public
Copyright
Other

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