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Hydrogen atom scrambling in ion-molecule reactions of methane and ethylene.The extent of hydrogen atom exchange in the reaction, CH3(+) + CH4 yields C2H5(+) + H2, is determined by examining the product distribution for the reactions CH3(+) + CD4 and CD3(+) + CH4 as a function of relative kinetic energy from thermal energies to 10 eV. It is found that the reaction of CH4(+) with the parent neutral proceeds both via proton transfer and hydrogen abstraction accompanied by approximately 10% hydrogen atom exchange during the reaction.
Document ID
19720046856
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Huntress, W. T., Jr.
(California Institute of Technology, Jet Propulsion Laboratory, Pasadena Calif., United States)
Date Acquired
August 6, 2013
Publication Date
May 15, 1972
Publication Information
Publication: Journal of Chemical Physics
Volume: 56
Subject Category
Chemistry
Accession Number
72A30522
Distribution Limits
Public
Copyright
Other

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