Upper atmospheric probing by resonance fluorescence excited by tunable laser radiation.

Consideration of the application of the measurement of resonance fluorescence radiation excited by tunable laser radiation to the detection of atomic, molecular, and ionic species in the upper atmosphere. The species considered are N2, N2(+), NO, NO(+), O2(+), CO, CO(+), CH, Na, K, and Ca. Calculations of the resonance scattering cross sections, photon returns, and signal-to-noise ratios are given for these species for a range of conditions. Based on a probing altitude of 100 km, the detections of N2, NO, CO, CH, O2, and the trace metals appear feasible with state-of-the-art systems and within the concentration range present in the atmosphere.