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A simple, radially correlated ground state wavefunction for two electron atoms.A one parameter function is presented as an approximation to the ground state wavefunction of the two electron radial hamiltonian. The parameter may be fixed by a nonvariational criterion. The resulting expectation value of the radial hamiltonian differs from its exact eigenvalue by about 2 parts in 3000 for helium while the 'local energy' never differs by more than 10% from the exact value over the entire r1-r2 plane. The cases Z = 1 and Z = 3 are also investigated.
Document ID
19720052162
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Altick, P. L.
(Nevada, University Reno, Nev., United States)
Date Acquired
August 6, 2013
Publication Date
June 1, 1972
Publication Information
Publication: Journal of Physics
Subject Category
Physics, Atomic, Molecular, And Nuclear
Accession Number
72A35828
Distribution Limits
Public
Copyright
Other

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