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A flash photolysis-resonance fluorescence kinetics study of the reaction S/3P/ + OCSUsing the technique of flash photolysis-resonance fluorescence, the reaction of ground-state atomic sulfur with carbonyl sulfide has been investigated over the temperature range from 233 to 445 K. Over this temperature range, the experimental data were fitted to an Arrhenius equation of the form k sub 1 = (1.52 plus or minus 0.20) x 10 to the minus 12th power exp(-3.63 plus or minus 0.12 kcal/mol/RT) cu cm/molecule/sec. A comparison of these results with previous investigations on this reaction system is presented.
Document ID
19740052265
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Klemm, R. B.
(NASA Goddard Space Flight Center Astrochemistry Branch, Greenbelt; Maryland, University, College Park, Md., United States)
Davis, D. D.
(Maryland, University College Park, Md., United States)
Date Acquired
August 7, 2013
Publication Date
June 6, 1974
Publication Information
Publication: Journal of Physical Chemistry
Volume: 78
Subject Category
Chemistry
Accession Number
74A35015
Distribution Limits
Public
Copyright
Other

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