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Orientational invariance of the rotational transition probability in the sudden approximationSemiclassical collisions of an atom with a rigid-rotor molecule are examined in the sudden approximation. The rotational transition probability is shown to be invariant with respect to the choice of orientation for the molecular coordinate system; this fact contradicts recently reported results of a computer analysis. The present analysis may lead to an improved interpretation of recent molecular beam measurements.
Document ID
19750031493
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Stallcop, J. R.
(NASA Ames Research Center Moffett Field, Calif., United States)
Date Acquired
August 8, 2013
Publication Date
September 1, 1974
Publication Information
Publication: Chemical Physics
Volume: 5
Subject Category
Atomic And Molecular Physics
Accession Number
75A15565
Distribution Limits
Public
Copyright
Other

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