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Absolute rate constant determinations for the deactivation of O/1D/ by time resolved decay of O/1D/ yields O/3P/ emissionAbsolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined by observing the time-resolved emission of O(1D) at 630 nm. O(1D) atoms were produced by the dissociation of ozone via repetitive laser pulses at 266 nm. Absolute rate constants for the relaxation of O(1D) at 298 K are reported for N2, O2, CO2, O3, H2, D2, CH4, HCl, NH3, H2O, N2O, and Ne. The results obtained are compared with previous relative and absolute measurements reported in the literature.
Document ID
19760034386
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Davidson, J. A.
(National Bureau of Standards Boulder, CO, United States)
Sadowski, C. M.
(National Bureau of Standards Boulder, CO, United States)
Schiff, H. I.
(York University Toronto, Canada)
Howard, C. J.
(National Bureau of Standards Boulder, CO, United States)
Schmeltekopf, A. L.
(NOAA, Aeronomy Laboratory, Boulder Colo., United States)
Jennings, D. A.
(NOAA, Aeronomy Laboratory, National Bureau of Standards, Boulder Colo., United States)
Streit, G. E.
(National Bureau of Standards Boulder, CO, United States)
Date Acquired
August 8, 2013
Publication Date
January 1, 1976
Publication Information
Publication: Journal of Chemical Physics
Volume: 64
Subject Category
Nuclear And High-Energy Physics
Accession Number
76A17352
Funding Number(s)
CONTRACT_GRANT: NGR-52-134-005
Distribution Limits
Public
Copyright
Other

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