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O/S-1/ interactions - The product channelsThe first measurements are reported of the reaction pathways for the interaction between oxygen atoms in the 4.19 eV S-1 state, and four molecules, N2O, CO2, H2O, and NO. Distinction is made between three possible paths - quenching to O(D-1), quenching to O(P-3), and chemical reaction. With N2O, the most reasonable interpretation of the data indicates that there no reaction, in sharp contrast with the interaction between O(D-1) and N2O, which proceeds entirely by reaction. Similarly, there is no reaction with CO2. With H2O, the reactive pathway is the dominant one, although electronic quenching is not negligible. With NO, O(D-1) is the preferred product.
Document ID
19780042222
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Slanger, T. G.
(SRI International Corp. Menlo Park, CA, United States)
Black, G.
(SRI International Menlo Park, Calif., United States)
Date Acquired
August 9, 2013
Publication Date
February 1, 1978
Publication Information
Publication: Journal of Chemical Physics
Volume: 68
Subject Category
Atomic And Molecular Physics
Accession Number
78A26131
Funding Number(s)
CONTRACT_GRANT: DAHC04-74-C-0003
CONTRACT_GRANT: NASW-2849
Distribution Limits
Public
Copyright
Other

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