The production and treatment of gaseous pollutants in an electrostatic precipitator

The production of ozone and nitric oxides and the oxidation of two organic contaminants, methane and acetylene, were studied in the corona discharge of a model cylindrical electrostatic precipitator. Both air and oxygen streams were passed through the discharge while current, voltage, electrode/wall radius ratio, residence time and wall temperature were varied. Under all conditions using air, much more ozone was produced in the negative than in the positive corona, in agreement with qualitative data reported in the literature. However, using oxygen, as much as three to four times more ozone is produced by the positive corona. Over a wide range of conditions ozone production is proportional to current. Limited analyses of nitric oxides formation in air indicated that levels were higher in the negative than in the positive corona. In contrast to previous work using an RF discharge, methane contamination was not removed by the corona discharge. However, the oxidation of acetylene was affected by the discharge and could not be accounted for by homogeneous ozonation alone.