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Field ionization kinetic and electron impact studies of gas phase transition states - The cyclic bromonium ionCis- and trans-isomers of 4-t-butylcyclohexyl bromide were studied to determine the mechanism of cyclic bromonium ion formation. The field ionization kinetic and electron impact data indicate that the formation of the cyclic structure occurs simultaneously with loss of the neutral fragment. The data also show that little or no gas-phase cis-trans isomerization occurs.
Document ID
19780067965
Acquisition Source
Legacy CDMS
Document Type
Other - Collected Works
Authors
Green, M. M.
(Michigan State Univ. East Lansing, MI, United States)
Giguere, R. J.
(Michigan State University East Lansing, Mich., United States)
Falick, A. M.
(Michigan State Univ. East Lansing, MI, United States)
Aberth, W.
(Michigan State Univ. East Lansing, MI, United States)
Burlingame, A. L.
(California, University Berkeley, Calif., United States)
Date Acquired
August 9, 2013
Publication Date
January 1, 1978
Subject Category
Inorganic And Physical Chemistry
Accession Number
78A51874
Funding Number(s)
CONTRACT_GRANT: NSF MPS-72-05129-A02
CONTRACT_GRANT: NGL-05-003-003
Distribution Limits
Public
Copyright
Other

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