Temperature effect on nitrogen-induced absorption of oxygen in the Herzberg continuum

The effect of temperature on the total absorption of O2 induced by collisions with N2 has been measured at various temperatures in the Herzberg continuum using a one-meter normal-incidence grating monochromator. It is observed that absorption increases as the temperature decreases, which is ascribed to changes in the rate of formation of the dimers O2-O2 and O2-N2. The interaction constants for these dimers are determined as functions of temperature and then utilized to calculate the heats of dissociation of O2-O2 and O2-N2. Their respective values are found to be 0.0146 + or - 0.001 and 0.425 + or - 0.002 eV. Also, the interaction constants for these dimers measured at 200 + or - 1 K are utilized to investigate their effect on the absorption of solar radiation in the stratosphere.