Kinetics of hydrogen-oxygen and methane-oxygen ignition sensitized by NO or NO2In a study of methane ignition sensitized by NO2, the induction period chemical kinetics were examined by monitoring reactants and intermediates (CH4, NO2, OH, NO, CO, CO2, and H2O) prior to ignition. Data were obtained at pressure of 2-4 atm, temperatures of 1300-1900 K, equivalence ratios of 0.5-1.0, and NO2 up to 3.4 mole %. A tentative NO2 sensitization mechanism was deduced from the analysis of photometric observations and the comparison of computer modeling with observations.
Document ID
19790031238
Acquisition Source
Legacy CDMS
Document Type
Conference Proceedings
Authors
Slack, M. W. (Grumman Aerospace Corp. Bethpage, NY, United States)
Grillo, A. R. (Grumman Aerospace Corp. Research Dept., Bethpage, N.Y., United States)
Date Acquired
August 9, 2013
Publication Date
January 1, 1978
Subject Category
Inorganic And Physical Chemistry
Meeting Information
Meeting: Shock tube and shock wave research; Eleventh International Symposium