The response of stratospheric constituents to a solar eclipse, sunrise, and sunset

The use of measurements combined with detailed stratospheric modeling of time dependent events, to confirm chemical mechanisms and their laboratory rate constants, is examined. Careful simultaneous solutions of these equations have shown a significant daytime variation of ozone down to altitudes of about 30 km that can affect the interpretation of spectral absorption type experiments. The calculated sunset variations of NO and HO show a log linear concentration decay for limited time periods that can be readily converted into atmospheric temperatures by using known reaction rates up to about 70-km altitude. Proposed measurements of the time dependent behavior of NO and NO2 to be made by U2 aircraft at 20-km altitude are also discussed.