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Electrochemical fluorination of trichloroethylene and N, N-dimethyltrifluoroacetamideThe paper presents the results of experiments concerning the fluorination of trichloroethylene and N, N-dimethyltrifluoroacetamide carried out on a laboratory scale in an advanced 'Simons' type electrochemical apparatus which could be operated automatically from ambient to 50 psi pressure. It is shown that a variety of fluorine-substituted products are formed, depending upon electrolysis conditions and concentrations of reactant relative to the NaF, KF, HF electrolyte. A new reaction mechanism of electrochemical fluorination of trichloroethylene is proposed. Finally, the solvency-to-fluorine content relationship of fluorinated N, N-dimethyltrifluoroacetamide is described.
Document ID
19790065523
Acquisition Source
Legacy CDMS
Document Type
Conference Paper
Authors
Hsu, L.-C.
(NASA Lewis Research Center Cleveland, Ohio, United States)
Date Acquired
August 9, 2013
Publication Date
May 1, 1979
Subject Category
Chemistry And Materials (General)
Meeting Information
Meeting: Electrochemical Society, Meeting
Location: Boston, MA
Start Date: May 6, 1979
End Date: May 11, 1979
Sponsors: Electrochemical Society
Accession Number
79A49536
Distribution Limits
Public
Copyright
Other

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