NASA Logo

NTRS

NTRS - NASA Technical Reports Server

Back to Results
F + H2 collisions on two electronic potential energy surfaces - Quantum-mechanical study of the collinear reactionCollinear quantum calculations are carried out for reactive F + H2 collisions on two electronic potential energy surfaces. The resulting transmission and reflection probabilities exhibit much greater variation with energy than single-surface studies would lead us to anticipate. Transmission to low-lying product channels is increased by orders of magnitude by the presence of the second surface; however, branching ratios among product states are found to be independent of the initial electronic state of the reactants. These apparently contradictory aspects of the calculation are discussed and a tentative explanation put forward to resolve them.
Document ID
19800027842
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
Authors
Zimmerman, I. H.
(Clarkson College of Technology Potsdam, N.Y., United States)
Baer, M.
(Atomic Energy Commission, Soreq Nuclear Research Centre Yavne; Weizmann Institute of Science, Rehovot, Israel)
George, T. F.
(Clarkson Coll. of Technology Potsdam, NY, United States)
Date Acquired
August 10, 2013
Publication Date
November 15, 1979
Publication Information
Publication: Journal of Chemical Physics
Volume: 71
Subject Category
Atomic And Molecular Physics
Report/Patent Number
AFOSR-TR-79-1333
AD-A080702
Accession Number
80A12012
Funding Number(s)
CONTRACT_GRANT: NSF CHE-77-27826
CONTRACT_GRANT: F49620-78-C-0005
CONTRACT_GRANT: NSG-2198
Distribution Limits
Public
Copyright
Other

Available Downloads

There are no available downloads for this record.
No Preview Available