A mechanism for the compressive ignition of liquid monopropellants

Possible mechanisms for compressive ignition of liquid monopropellants are discussed. These mechanisms all involve the collapse of a gas filled bubble imbedded in the liquid. A model of the collapse of a gas bubble in an incompressible liquid and the combustion of the surrounding liquid after ignition occurs is presented. The effect of gas covolume, liquid density, the adiabatic exponent, rate of pressurization and prepressurization are investigated. Calculations for finite and infinite liquid volumes are also presented. Gas generation in the bubble is shown to have a significant effect on its evolution and the introduction of a surface enhancement factor leads to a runaway reaction. For the conditions considered, the reacting bubble oscillates at a frequency of about 35 kHz over the first 0.5 milliseconds. This frequency decreases as the surface enhancement factor is increased. The implication is that a one dimensional model of this process may be tractable from the standpoint of computer time.