Cross section for Ly-alpha emission by electron impact on methane

Utilizing Lyman-alpha emission cross sections for H2 as secondary standards, absolute values of Lyman-alpha emission cross sections for CH4 have been obtained for electron impact energies varying from threshold to 100 eV. A crossed electron beam-molecular beam geometry was employed and the Lyman-alpha radiation was detected at 90 deg and 45 deg with respect to the incident electron beam by a solar blind photomultiplier in tandem with an oxygen filter. The results are compared with previous measurements. Appreciable differences among the various experimental data are found.