Shock temperatures of SiO2 and their geophysical implications

High pressure shock state temperatures of SiO2 were measured in specimens of single crystal alpha-quartz and fused quartz. Projectile impact and pyrometry techniques were employed to impart pressures in the 60-140 GPa range. Shock-induced phase transformations were observed near 70 and 50 GPa along the alpha- and fused-quartz Hugoniots. It is suggested that the transformation consists of melting of the shock-synthesized stishovite, with melting delayed by the superheating of the crystalline phase. Details of the stishovite-liquid phase boundaries have been determined, including stishovite melting at 4500 K under 70 GPa, with the melting accompanied by a relative volume change of about 2.7% and a latent heat of fusion of about 2.4 MJ/kg. At 100 GPa, an approximate limit of 3500 K for the melting of SiO2 is indicated for solid mantle mineral assemblages, such as the earth's mantle