The Delta band dissociation of nitric oxide - A potential mechanism for coupling thermospheric variations to the mesosphere and stratosphere

Depletion of solar radiation at discrete wavelengths by nitric oxide has a significant impact on the dissociation rate of this gas in the delta(0, 0) and delta(1, 0) bands. Inclusion of the opacity provided by a typical NO profile reduces the dissociation rate in the upper stratosphere to 50-75 pct of that predicted when the optical depth calculation omits this contribution. A substantial fraction of the NO column abundance as measured near the stratopause resides in the lower thermosphere where correlations of NO with solar and magnetic activity are well documented. Variations in the thermospheric NO abundance therefore modulate the radiation field at the precise wavelengths absorbed by this molecule in the mesosphere and upper stratosphere. Predicted changes in the dissociation rate arising from a varying thermospheric opacity exceed 8 pct throughout the mesosphere and reach 15 pct between 65 km and 95 km.