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Chlorine nitrate - The sole product of the ClO + NO2 + M recombinationA laser operating at 266 nm is used to photolyze the product of the ClO + NO2 + M reaction, and the yield of Cl atoms, measured by resonance fluorescence, is found to be identical with that from equivalent concentrations of ClONO2. This is interpreted as a strong indication that no other isomers are formed in the recombination reaction. Evidence for isomers is surveyed, and the apparent forward-and-reverse-rate constant discrepancy is explained as a probable uncertainty in the thermochemistry.
Document ID
19830054936
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Margitan, J. J.
(California Institute of Technology, Jet Propulsion Laboratory, Pasadena CA, United States)
Date Acquired
August 11, 2013
Publication Date
June 20, 1983
Publication Information
Publication: Journal of Geophysical Research
Volume: 88
ISSN: 0148-0227
Subject Category
Geophysics
Accession Number
83A36154
Distribution Limits
Public
Copyright
Other

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