Turbidity very near the critical point of methanol-cyclohexane mixtures

The turbidity of a critical mixture of methanol and cyclohexane has been measured extremely close to the consolute point. The data span the reduced-temperature range between 10 to the -7th and 10 to the -3d, which is two decades closer to Tc than previous measurements. In this temperature range, the turbidity varies approximately as 1nt, as expected from the integrated form for Ornstein-Zernike scattering. A thin cell (200-micron optical path) with a very small volume (0.08 ml) was used to avoid multiple scattering. A carefully controlled temperature history was used to mix the sample and to minimize the effects of critical wetting layers. The data are consistent with a correlation-length amplitude of 3.9 plus or minus 1.0 A, in agreement with the value 3.5 A calculated from two-scale-factor universality and heat-capacity data from the literature.