Thermal fields in the Bridgman-Stockbarger technique

Temperature measurements were made throughout a naphthalene melt and solid in a simulated Bridgman-Stockbarger apparatus. Heating and cooling were provided by agitated baths separated by a polymer diaphragm. While agitation was sufficient to give uniform temperatures in the baths, the level of agitation in the heater strongly influenced the results. Unlike theoretical results for high thermal conductivity materials, natural convection in the melt had a strong influence on interface position and on the temperature distribution. Isotherms were relatively flat in the solid and both curved and erratic in the melt. The interface became more convex as it was moved higher into the heating bath by raising either the heating bath or cooling bath temperatures. Using a one-dimensional model, the Biot number in the cooler was determined to be 0.03, that for the solid in the heater 0.008, and for the molten region in the heater 0.3. Biot numbers for two or three dimensional models would be significantly different.