On the theory of the conversion of metallic mixed phases. 5: Fluctuations and nucleation in sub-cooled phases

A comparison is made between fluctuation-theoretical calculations and empirical results. Concentration fluctuations and the resulting separation, and the distribution function of the reversible fluctuations are approximately calculated. The relation of this distribution to the concentration-dependence of the free energy is discussed. Possible effects of fluctuations are discussed, and other attempts to explain the sub-cooling are described.