Deuterium fractionation in the presolar nebula - Kinetic limitations on surface catalysis

A quantitative test is presented for the possibility that grain-based catalysis could shorten the equilibration times of low temperature equilibrium fractionation sufficiently to account for the D/H ratio values of the solar system even at nebular temperatures. It is found that under the highly idealized conditions in which the full cosmic abundance of Ni is available for catalysis in pure, 5-micron grains, the equilibration time constant becomes greater than the nebular lifetime at temperatures below 560 K. This lower limit is not, however, sufficiently low to permit strong fractionation.