A basic limitation of the split window method for SST retrievals when applied to a wide range of water vapor conditions

The split window method for retrieving sea surface temperatures (SST) from satellite-based observations is evaluated from radiative transfer calculations, and shown to have an inherent limitation that arises from a linear assumption in the correction scheme. This general limitation leads to significant errors (of several degrees in some cases) in the retrieved SST; the theoretical basis for the error is examined.