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Kinetics and product studies of the reaction ClO + BrO using discharge-flow mass spectrometryThe kinetics and product branching ratios of the reaction between ClO and BrO were studied at 1 torr pressure over the temperature range 220-400 K, using the method of discharge-flow mass spectrometry. Three product channels were identified and quantified: Br + ClOO, Br + OClO, and BrCl + O2, indicating that the reaction mechanism of ClO + BrO involves metastable intermediates. The overall reaction rate coefficient and the rate coefficients for the three channel reactions are given.
Document ID
19900029235
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
External Source(s)
doi:10.1021/j100349a016
Authors
Friedl, Randall R. (Jet Propulsion Lab., California Inst. of Tech. Pasadena, CA, United States)
Sander, Stanley P. (JPL Pasadena, CA, United States)
Date Acquired
August 14, 2013
Publication Date
January 1, 1989
Publication Information
Publication: Journal of Physical Chemistry
Volume: 93
Issue: 12, 1
ISSN: 0022-3654
Subject Category
Inorganic And Physical Chemistry
Accession Number
90A16290
Distribution Limits
Public
Copyright
Other

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