Reconstruction of the constituent distribution and trends in the Antarctic polar vortex from ER-2 flight observations

The measurements of ozone, ClO, and N2O concentrations in the south polar region taken aboard the ER-2 aircraft during the Airborne Antarctic Ozone Experiment are analyzed using conservative coordinate transformations to potential temperature-N2O and potential temperature-potential vorticity space. The latter transformation is equivalent to interpreting trace species observations within the modified Lagrangian mean (MLM) coordinate system. The results show that the MLM transformed ozone concentration decreases at about 0.06 ppmv per day between 20- and 16-km altitude inside the polar vortex during the mid-August to mid-September period. These ozone changes are collocated with the region of high ClO concentration. Outside the chemically perturbed region, at the highest aircraft altitudes, ozone concentration systematically increases, suggesting a diabatic cooling of the order 0.3-0.6 K/day.