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Equilibrium polymerization on the equivalent-neighbor latticeThe equilibrium polymerization problem is solved exactly on the equivalent-neighbor lattice. The Flory-Huggins (Flory, 1986) entropy of mixing is exact for this lattice. The discrete version of the n-vector model is verified when n approaches 0 is equivalent to the equal reactivity polymerization process in the whole parameter space, including the polymerized phase. The polymerization processes for polymers satisfying the Schulz (1939) distribution exhibit nonuniversal critical behavior. A close analogy is found between the polymerization problem of index the Schulz r and the Bose-Einstein ideal gas in d = -2r dimensions, with the critical polymerization corresponding to the Bose-Einstein condensation.
Document ID
19900040551
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Kaufman, Miron
(Cleveland State University OH, United States)
Date Acquired
August 14, 2013
Publication Date
April 1, 1989
Publication Information
Publication: Physical Review B, 3rd Series
Volume: 39
ISSN: 0163-1829
Subject Category
Chemistry And Materials (General)
Accession Number
90A27606
Funding Number(s)
CONTRACT_GRANT: NSF DMR-86-20386
Distribution Limits
Public
Copyright
Other

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