The atmospheric sulfur cycle over the Amazon Basin. II - Wet season

The fluxes and concentrations of atmospheric sulfur species were determined at ground level and from aircraft over the Amazon Basin during the 1987 wet season, providing a comprehensive description of the sulfur cycle over a remote tropical region. The vertical profile of dimethylsulfide (DMS) during the wet season was found to be very similar to that measured during the dry season, suggesting little seasonal variation in DMS fluxes. The concentrations of H2S were almost an order of magnitude higher than those of DMS, which makes H2S the most important biogenic source species in the atmosheric sulfur cycle over the Amazon Basin. Using the gradient-flux approach, the flux of DMS at the top of the tree canopy was estimated. The canopy was a source of DMS during the day, and a weak sink during the night. Measurements of sulfur gas emissions from soils, using the chamber method, showed very small fluxes, consistent with the hypothesis that the forest canopy is the major source of sulfur gases. The observed soil and canopy emission fluxes are similar to those measured in temperate regions. The concentrations of SO2 and sulfate aerosol in the wet season atmosphere were similar to dry season values.