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High temperature reactions of ceramics and metals with chlorine and oxygenThe reactions of chlorine and oxygen with solids are complex and quite dependent on material and reaction conditions. However, there are four reaction schemes that describe many of these reactions. These are direct reaction of chlorine with the oxide layer, penetration of the oxide layer by chlorine, paralinear behavior where oxidation and chlorination are of comparable rates, and finally, gas phase reactions where the volatile chlorides react with oxygen. Examples of chlorine and oxygen reactions with cobalt, nickel, chromium, molybdenum, and silicon carbide illustrate each of these four reaction schemes.
Document ID
19910035596
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Jacobson, N. S.
(NASA Lewis Research Center Cleveland, OH, United States)
Mcnallan, M. J.
(Illinois, University Chicago, United States)
Kreidler, E. R.
(Ohio State University Columbus, United States)
Date Acquired
August 15, 2013
Publication Date
January 1, 1990
Publication Information
Publication: High Temperature Science
Volume: 27
ISSN: 0018-1536
Subject Category
Inorganic And Physical Chemistry
Accession Number
91A20219
Distribution Limits
Public
Copyright
Other

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