L-shell X-ray opacity of many-electron atoms

The study presents a formulation for obtaining the L-shell photoelectric cross section (sigma sub L) for many-electron atomic systems. A scaling law is suggested for the evaluation of the contribution to sigma sub L from 2s and 2p ejection from a general system in any ionization state. The formula is expressed in terms of the effective nuclear charge (Z sub 2s and Z sub 2p) seen by the corresponding bound electrons, with Z sub 2s and Z sub 2p, obtained from improved screening constants derived in a recent investigation. A comparison is made of Hartree-Fock and hydrogenic expressions for sigma sub L with experimental results for atomic neon at X-ray photon energies, providing the basis for the scaling law and an approximate energy dependence for the cross sections. The special case of sigma sub L for atomic Fe is considered in detail. This L edge has structure because of the different threshold for 2s and 2p photoejection; the latter has fine structure.