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Induced ClO vacuum ultraviolet fluorescenceSome vibronic transitions of ClO such as G(v-prime = 11 )-X(v-double prime = 10), G(v-prime = 5)-X(v-double prime = 3) and H(v-prime = 4)-X(v-double prime = 2), which promote overtones of X(2pi3/2) to bound Rydberg states, are nearly resonant with the 130.6 nm O-atom emission line and possess sizable Franck-Condon factors. On this basis broadband detection of 'O atom' fluorescence in experiments involving vibrationally excited ClO(X) is ascribed to the radiative decay of ClO(G, H) rather than to the formation of O atoms; these observations raise the probability of monitoring ClO(X; v = 0) by VUV-induced fluorescence.
Document ID
19930049045
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Colussi, A. J.
(Jet Propulsion Lab., California Inst. of Tech. Pasadena, CA, United States)
Sander, S. P.
(JPL Pasadena, CA, United States)
Date Acquired
August 16, 2013
Publication Date
November 29, 1991
Publication Information
Publication: Chemical Physics Letters
Volume: 187
Issue: 1-2
ISSN: 0009-2614
Subject Category
Inorganic And Physical Chemistry
Accession Number
93A33042
Distribution Limits
Public
Copyright
Other

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