Increased response of the reversal electron attachment detector and modeling of ion space-charge effects

Design and sensitivity tests of a modified version of the so-called reversal electron attachment detector (READ) are presented. The new version uses a spherical cathode capable of emitting higher electron currents. As in the original READ (which used a planar emitter) electrons are focused into an electrostatic mirror which reverses their trajectories. In the reversal region electrons have essentially zero energy and attach to target molecules to form negative ions. The electron gun lens system has been modified using a field and trajectory code with space charge included. Electron trajectories have been calculated for 1-mA current focused into a reversal region of 3.5-mm diameter. The detection limit of the apparatus is approximately 25 times lower than for the original READ. Nonlinearity in the measured signal vs electron current is described by a model in which a spherical ball of ions expands outward with velocity determined by the space-charge force and the initial velocity of ion formation.