Infrared spectra of transition objects and the composition and evolution of carbon dust

We obtained IR (5-23 microns) spectra of five carbon-rich objects in transition from the asymptotic giant branch (AGB) to the planetary nebula stage of evolution. These spectra show a variety of IR emission features due to circumstellar materials. In particular, all sources show the 6.2 and '7.7' micron bands, commonly observed in PNs and ascribed to polycyclic aromatic hydrocarbon molecules (PAHs). Some transition nebulae also show a strong 6-9 micron plateau characteristic for larger PAH clusters (about 400 C-atoms). A new broad feature at about 8.8 microns is present in some sources. This feature is distinctly different from the 8.6-micron PAH feature. This 8.8-micron feature may be present in the spectra of C-rich giants as well, but is not evident in PN spectra. We suggest that large amorphous carbon grains are responsible for the 8.8-micron feature. The transition objects show large spectral variations from source to source. This contrasts with C-rich PNs, which all show very similar IR spectra dominated by PAHs. These spectral variations between transition objects of similar effective temperatures cannot be due to excitation variations but imply compositional variations of the dust. Moreover, this result suggests that circumstellar dust evolves during the transition phase from red giant to PN, perhaps as a result of grain-grain collisions and shattering in the fast winds.