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Storage and recycling of water and carbon dioxide in the earthThe stabilities and properties of water- and carbon-bearing phases in the earth have been determined from phase equilibrium measurements, combined with new data on the equations of state of water, carbon dioxide, carbonates and hydrates. The data have then been used to predict the fate of calcite and hydrous phases in subducting oceanic lithosphere. From the compositions of MORB's one can estimate concentrations of water and carbon of around 200 ppm and 80 ppm respectively in the upper mantle. Lower mantle estimates are very uncertain, but 1900 ppm water and 2000 ppm C are plausible concentrations. Measurements of the density of supercritical water to 3 GPa demonstrate that this phase is less compressible than anticipated from the equations of state of Haar et al. or Saul and Wagner and is closer to predictions based on molecular dynamics simulations. Conversely, fugacity measurements on carbon dioxide to 7 GPa show that this fluid is more compressible than predicted from the MRK equation of state. The results imply that hydrates are relatively more stable and carbonates less stable at pressures greater than 5 GPa than would be predicted from simple extrapolation of the low pressure data. Nevertheless, carbonates remain extremely refractory phases within both the upper and lower mantle.
Document ID
19950015405
Acquisition Source
Legacy CDMS
Document Type
Conference Paper
Authors
Wood, Bernard J.
(Bristol Univ.)
Date Acquired
September 6, 2013
Publication Date
January 1, 1994
Publication Information
Publication: Lunar and Planetary Inst., Conference on Deep Earth and Planetary Volatiles
Subject Category
Geophysics
Accession Number
95N21822
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.

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