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Electronic transition moment for the B(2)II-X(2)II system of NOThe upsilon' = 0-3 and 7 vibrational levels of the NO B(2)II state have been selectively excited by laser radiation. The fluorescence spectra together with calculated Franck-Condon factors and r-centroids have been used to evaluate the electronic transition moment. The results for upsilon' = 0-3 are in very good agreement with recent chemiluminescence measurements and ab initio calculations. Furthermore, the data from upsilon' = 7 have been used to extend the empirically determined moment to limits 1.23 and 1.78 A, improving agreement with experimentally determined lifetimes.
Document ID
19950056398
Acquisition Source
Legacy CDMS
Document Type
Reprint (Version printed in journal)
Authors
Luque, Jorge
(SRI International, Menlo Park, CA United States)
Crosley, David R.
(SRI International, Menlo Park, CA United States)
Date Acquired
August 16, 2013
Publication Date
February 1, 1995
Publication Information
Publication: Journal of Quantitative Spectroscopy & Radiative Transfer
Volume: 53
Issue: 2
ISSN: 0022-4073
Subject Category
Solid-State Physics
Accession Number
95A87997
Distribution Limits
Public
Copyright
Other

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