NASA Logo

NTRS

NTRS - NASA Technical Reports Server

Back to Results
Kinetics of the Reaction of O((sup 3)P) with CF3NOA laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O((sup 3)P) with CF3NO (k(2)) as a function of temperature. Our results are described by the Arrhenius expression k(2)(T) = (4.54 +/- 0.70) x 10(exp -l2)exp[(-560 +/- 46)/T] cu cm/molecule.s (243 K is less than or equal to T is less than or equal to 424 K); errors are 2 sigma and represent precision only. The O((sup 3)P) + CF3NO reaction is sufficiently rapid that CF3NO cannot be employed as a selective quencher for O2(alpha(1) Delta-g) in laboratory systems where O((sup 3)P) and O2(alpha 1 Delta g) coexist, and where O((sup 3)P) kinetics are being investigated.
Document ID
19980015256
Acquisition Source
Headquarters
Document Type
Reprint (Version printed in journal)
Authors
Thorn, R. P.
(Georgia Inst. of Tech. Atlanta, GA United States)
Nicovich, J. M.
(Georgia Inst. of Tech. Atlanta, GA United States)
Cronkhite, J. M.
(Georgia Inst. of Tech. Atlanta, GA United States)
Wine, P. H.
(Georgia Inst. of Tech. Atlanta, GA United States)
Date Acquired
August 17, 2013
Publication Date
April 9, 1997
Publication Information
Publication: Laboratory Investigations of Stratospheric Halogen Chemistry
Publisher: John Wiley and Sons, Inc.
ISSN: 0538-8066
Subject Category
Inorganic And Physical Chemistry
Funding Number(s)
CONTRACT_GRANT: NAGw-1001
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
Document Inquiry

Available Downloads

There are no available downloads for this record.
No Preview Available