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Deuterium Substitution used as a Tool for Investigating Mechanisms of Gas-Phase Free-Radical ReactionsResults are presented and discussed for a number of gas phase free radical reactions where H/D isotope effects provide valuable mechanistic insights. The cases considered are (1) the reactions of OH, NO3, and Cl with atmospheric reduced sulfur compounds, (2) the reactions of OH and OD with CH3CN and CD3CN, and (3) the reactions of alkyl radicals with HBr and DBr.
Document ID
19980015262
Acquisition Source
Headquarters
Document Type
Reprint (Version printed in journal)
Authors
Wine, P. H.
(Georgia Tech Research Inst. Atlanta, GA United States)
Hynes, A. J.
(Georgia Tech Research Inst. Atlanta, GA United States)
Nicovich, J. M.
(Georgia Tech Research Inst. Atlanta, GA United States)
Date Acquired
August 17, 2013
Publication Date
April 9, 1997
Publication Information
Publication: Laboratory Investigations of Stratospheric Halogen Chemistry
Publisher: American Chemical Society
ISSN: 0097-6156
Subject Category
Inorganic And Physical Chemistry
Meeting Information
Meeting: Isotope Effects in Gas-Phase Chemistry
Location: Atlanta, GA
Country: United States
Start Date: April 14, 1991
End Date: April 19, 1991
Sponsors: American Chemical Society
Funding Number(s)
CONTRACT_GRANT: NSF ATM-8600892
CONTRACT_GRANT: NAGw-1001
CONTRACT_GRANT: NSF ATM-8217232
Distribution Limits
Public
Copyright
Work of the US Gov. Public Use Permitted.
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