Pulse Stripping Analysis: A Technique for Determination of Some Metals in Aerosols and Other Limited Size Samples

A technique for determining lead with a detection limit down to a nanogram on limited size samples is described. The technique is an electrochemical one and involves pre-concentration of the metal species in a mercury drop. Although the emphasis in this paper is on the determination of lead, many metal ion species which are reducible to the metal at an electrode are equally determinable. A technique called pulse polarography is proposed to determine the metals in the drop and this technique is discussed and is compared with other techniques. Other approaches for determination of lead are also compared. Some data are also reported for the lead content of Ventura County particulates. The characterization of lead species by solubility parameters is discussed.