Photochemistry of Oxygen Compounds in Neptune's Stratosphere

ISO SWS observations of H2O and CO2 on Neptune (Feuchtgruber et al. 1997, Nature 389, 159) coupled with ground based millimeter observations of CO (Marten et al., 1993, Ap. J. 406 285) provide strong constraints on the photochemistry of these compounds in Neptune's stratosphere. Additional constraints on the photochemistry and vertical mixing come from the rich suite of hydrocarbons observed by ISO: CH4, C2H2, C2H6 (Bezard, 1998, Ann. Geophysicae 16, Sup. III C1037), CH3 (Bezard, et al. Ap. J. 515, 868), and C2H4 (Encrenaz et al. this DPS). We will use a one-dimensional global average photochemical model to analyze these compounds. In particular, we will better constrain the estimated external flux of H2O to Neptune's stratosphere given in Feuchtgruber et al., which is important in understanding the source of the observed stratospheric CO2. Kingdoms will come and go, the relentless march of time will continue, all will be explained.