Estimates of Spectral UV Irradiance from Earth Probe TOMS: Comparisons with Ground-Based Measurements

Estimates of the spectral UV flux incident on the Earth's surface are calculated based on total column ozone and cloud optical thickness determined from the Earth Probe Total Ozone Mapping Spectrometer (TOMS) satellite data. Spectral fluxes are calculated between 300 and 325 nanometers using a weighting function similar to the measured function of the Brewer Spectrophotometer. Comparisons of the TOMS-derived values with ground-based Brewer Spectrophotometer measurements at 3 locations from the Canadian Brewer network (Toronto, Saskatoon and Saturna Island) and 3 locations from the United States EPA network (Boston, Gaithersburg, and Boulder) show reasonably good agreement over a variety of clear and cloudy conditions. Some systematic differences are apparent, particularly when snow/ice is present and the TOMS instrument cannot distinguish between clouds and snow covered ground, thus leading to an underestimation of UV flux. The presence of absorbing aerosols near the ground or sub-pixel clouds can also lead to significant errors. There are also possible errors in the Brewer data due to radiometric calibration uncertainties and uncorrected cosine response.