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Point Defect Distributions in ZnSe Crystals: Effects of Gravity Vector Orientation During Physical Vapor Transport GrowthZnSe crystals were grown by the physical vapor transport technique under horizontal and vertical (stabilized and destabilized) configurations. Secondary ion mass spectroscopy and photoluminescence measurements were performed on the grown ZnSe samples to map the distributions of [Si], [Fe], [Cu], [Al] and [Li or Na] impurities as well as Zn vacancy, [V (sub Zn)]. Annealings of ZnSe under controlled Zn pressures were studied to correlate the measured photoluminescence emission intensity to the equilibrium Zn partial pressure. In the horizontal grown crystals the segregations of [Si], [Fe], [Al] and [V (sub Zn)] were observed along the gravity vector direction whereas in the vertically stabilized grown crystal the segregation of these point defects was radially symmetrical. No apparent pattern was observed on the measured distributions in the vertically destabilized grown crystal. The observed segregations in the three growth configurations were interpreted based on the possible buoyancy-driven convection in the vapor phase.
Document ID
20000012409
Acquisition Source
Marshall Space Flight Center
Document Type
Reprint (Version printed in journal)
Authors
Su, Ching-Hua
(NASA Marshall Space Flight Center Huntsville, AL United States)
Feth, S.
(NASA Marshall Space Flight Center Huntsville, AL United States)
Hirschfeld, D.
(New Mexico Inst. of Mining and Technology Socorro, NM United States)
Smith, T. M.
(New Mexico Inst. of Mining and Technology Socorro, NM United States)
Wang, Ling Jun
(Tennessee Univ. Chattanooga, TN United States)
Volz, M. P.
(NASA Marshall Space Flight Center Huntsville, AL United States)
Lehoczky, S. L.
(NASA Marshall Space Flight Center Huntsville, AL United States)
Date Acquired
August 19, 2013
Publication Date
January 1, 1999
Publication Information
Publication: Journal of Crystal Growth
Publisher: Elsevier Science B.V.
Volume: 204
ISSN: 0022-0248
Subject Category
Solid-State Physics
Distribution Limits
Public
Copyright
Other

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