Calculated Half-widths and Line Shifts of Water Vapor Transitions in the 0.7- Micron Region and a Comparison with Published Data

Pressure-broadened half-widths and pressure-induced line shifts for the two most important bands of water vapor in the 0.7-micron region are determined using the complex Robert-Bonamy (CRB) formalism. The calculations are made with nitrogen and oxygen as the perturbing gas from which values for air as the perturbing gas are determined. The intermolecular potential is taken as a sum of electrostatic contributions and Lennard-Jones (6-12) atom-atom, and isotropic induction and dispersion components. The dynamics of the collision process are correct to second order in time. The calculated values are compared with published measurements and agreement is observed for both half-widths and line shifts. The temperature dependence of the half-width, which is necessary for reduction of remotely sensed data, is determined.