Microphysical Modelling of Polar Stratospheric Clouds During the 1999-2000 Winter

The evolution of the 1999-2000 Arctic winter has been examined using a microphysical/photochemical model run along diabatic trajectories. A large number of trajectories have been generated, filling the vortex throughout the region of polar stratospheric cloud (PSC) formation, and extending from November until the vortex breakup, in order to provide representative sampling of the evolution of PSCs and their effect on stratospheric chemistry. The 1999-2000 winter was particularly cold, allowing extensive PSC formation. Many trajectories have ten-day periods continuously below the Type I PSC threshold; significant periods of Type II PSCs are also indicated. The model has been used to test the extent and severity of denitrification and dehydration predicted using a range of different microphysical schemes. Scenarios in which freezing only occurs below the ice frost point (causing explicit coupling of denitrification and dehydration) have been tested, as well as scenarios with partial freezing at warmer temperatures (in which denitrification can occur independently of dehydration). The sensitivity to parameters such as aerosol freezing rates and heterogeneous freezing have been explored. Several scenarios cause sufficient denitrification to affect chlorine partitioning, and in turn, model-predicted ozone depletion, demonstrating that an improved understanding of the microphysics responsible for denitrification is necessary for understanding ozone loss rates.